Published October 2017

Heteroatomic compounds of curative Naftalan oil

B.A. Huseynova

B.M. Aliyev

N.F. Gafarova

F.I. Samadova

E.A. Bekhmetova

Keywords:  
Naftalan oil
oil fractions
heteroatomic and azotic compounds of basic character
acids
chromatographic adsorption
silica gel
eluent solvents
proton-magnetic resonance

The paper presents the results of study of structural-group composition of acids, phenols, and azotic compounds of basic character of Naftalan curative oil. From the Naftalan curative oil fractions with 200-3500 C boiling temperature were separated concentrates of acids, phenols and azotic compounds, the compositions of which were simplified via eluent chromatography using active silica gel and solvents with different polarity in the form of adsorbent. The structural-curative group composition of narrow fraction of Naftalan curative oil heteroatomic compounds has been studied via proton-magnetic resonance method. Obtained results showed that either Naftalan curative oil itself is rich with saturated (generally with naphthenic) hydrocarbons, or in its heteroatomic components molecules are revealed many substituents, residuals of naphthenic and alkali character.

Links