Published May 2020, Pg. 48-52

Section: Oil refining and petroleum chemistry

UOT: 665.612.2 – 027.22

DOI: 10.37474/0365-8554/2020-5-48-52

Oxidative desulphurization of gasoline fractions from Azerbaijani oils

Kh.I. Talybova

S.F. Ahmadbeyova

N.K. Andryushchenko

Z.B. Babaeva

L.M. Mirzaeva

S.G. Unusov

Keywords:  
oxidative desulphurization
extraction of sulfur-oxidative compounds with ion fluids
catalytic cracking and coking gasolines
desulphurization degree
octane number

The paper studies the process of oxidative desulphurization of catalytic cracking and coking gasoline types and their close cut fractions. Direct oxidation studies of these gasoline fractions using hydrogen peroxide in the presence of heterogenic catalysts containing Mo and Co ions have been carried out for the oxidation of sulfur compounds and their further extraction via ion fluids enabling extraction of sulfur-organic compounds in the form of concentrates of oily sulfoxides and sulfanoles. Thus, desulfurization degree of gasoline fractions comprises 70-80 % - ultimately without change in gasoline octane number.

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