Published November 2021, Pg. 43-48

Section: Oil refining and petroleum chemistry

UOT: 665.612б2-027.22

DOI: 10.37474/0365-8554/2021-11-43-48

Compositional analysis of light oil fractions from deep-water Guneshli field

B.A. Huseynova Dr. in Ch. Sc. - Institute for Petrochemical Processes

A.D. Guliyev Cand. in Ch. Sc. - Institute for Petrochemical Processes

B.M. Aliyev Cand. in Phis.-Math. Sc. - Institute for Petrochemical Processes

Hydrocarbon composition of the fraction with 150–300 оС boiling point of oil from deep-water Guneshli field has been studied. The oil is characterized with light, oily, low sulphur, low-in-tar, paraffinic structure (3.7 % mass of solid paraffin), without asphaltenes.

The fraction with 250–300 оС boiling point has been divided into naphteno-paraffinic and aromatic hydrocarbon groups using the method of liquid elution-adsorption chromatography. The individual hydrocarbon composition of naphteno-paraffinic hydrocarbons has been studied via chromato-mass-spectroscopy and the structure-group composition of the arenes using PMR-spectroscopy, correspondingly.

Isoprenoid С13С15 and С18, as well as 0.54 % mass of pristane biomarkers (С19) and phytane (С20) biomarkers have been revealed in the composition of naphteno-paraffinic hydrocarbons. the nuclear are enriched in the paraffinic structures in the form of substituent.

References:

1. Yusifzadeh Kh.B. The current state of oil and gas industry and future perspectives // Azerbaidzhanskoe neftyanoe khozaistvo, 2016, No 1, s. 10-16.

2. Guseynova A.N., Khuduyeva G.M. Sravnitel´naya kharakteristika litologicheskogo sostava i kollektorskikh svoistv porod mestorozhdeniy Guneshli i Kyapaz // Azerbaidzhanskoe neftyanoe khozaistvo, 2016, No 07-08, s. 11-15.

3. Bushnev D.A., Burdel´naya N.S. Nefti i organicheskoe veshchestvo pozdnedevonskikh  otlozheniy timano-pecherskogo basseina, sopostavlenie po molekulyarnym i izotopnym dannym // Neftekhimiya, 2015, t. 55, No 5, s. 775-382.

4. Petrov A.A. Uglevodorody nefti. – M.: Nauka, 1984, 264 s.

5. Samedova F.I., Guseynova B.A., Gasanov G.M., Aliyev B.M. Komponentniy sostav vakuumnykh ostatkov
(> 450 оC) neftey mestorozhdeniy Azeri, Guneshli // Neftepererabotka i neftekhimiya, 2015, No 7, s. 13-16.

6. Kirillov A.V., Petrov V.V. Ispol´zovanie khromatographicheskogo i khromato-mass-spektrometricheskogo metoda dlya analiza benzinovykh fraktsiy // Neftepererabotka i neftekhimiya, 2014, No 6, s. 19-26.

7. Kam´yanov V.F., Bol´shakov G.F. Opredelenie strukturnykh parametrov pri strukturno-gruppovom analize komponentov nefti // Neftekhimiya, 1984, t. 24, No 4, s. 450-459.

8. Samedova F.I., Guseynova B.A., Aliyeva F.Z. Osobennosti gruppovogo i gomologicheskogo sostava aromaticheskikh uglevodorodov ryada neftey Azerbaidzhana // Neftekhimiya, 2009, t. 49, No 6, s. 466-472.

9. Samedova F.I., Guseynova B.A., Kuliyev A.D., Gasanova G.M. Uglevodorody nefti glubokovodnogo mestorozhdeniya Guneshli // Mir nefteproduktov, 2016, No 8, s. 26-29.

Links