Published January 2023, Pg. 40-44

Section: Oil refining and petroleum chemistry

UOT: 547.313.2

DOI: 10.37474/0365-8554/2023-1-40-44

The synthesis and study of monomers of cyclohexyl(met)acrilates

I.M. Guliyeva PhD in Ch. Sc. - Institute for Petrochemical Processes

The paper deals with the reaction of the eterification of cyclohexanole with (met)acrilate acids in the presence of a new catalytic system – the catalyst of sulfocationite type, sulfate derivatives of poliolefines with styrole (co)polymers. As a result of the reaction of eterification, the cyclohexyl(met)acrilate monomers were synthesized correspondingly. The eterification reactions of the synthesis of cyclohexyl(met)acrilate esters  were carried out in the presence of KU-2-8-, KU-23 catalysts as well. The reactions of eterification were conducted in various conditions – with different mole ratio of the primary components and in the presence of various catalysts. As the products obtained are transparent, but some of them are oily and sticky, we can suppose that they contain not only cyclohexyl(met)acrilates but oligomer products as well. In this regard, some products may be characterized as oligocyclohexyl(met)acrilate compounds. The initial results obtained from the analysis of thermo-physical and spectroscopic parameters of synthesized products are presented, on the basis of which, the development of composite compounds is planned.

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