Published May 2023, Pg. 49-55

Section: Oil refining and petroleum chemistry

UOT: 66.094.3-926-217, 544.431

DOI: 10.37474/0365-8554/2023-5-49-55

Formation products from the n-undecane oxidation reaction

U.A. Karimova PhD in Ch. Sc. - National Academy of Sciences of Azerbaijan Republic Institute of Petrochemical Processes

Keywords:  
n-undecane
liquid-phase aerobic oxidation
oxidation mechanism
synthetic fatty acids

This paper presents a study of the reaction products of the liquid-phase aerobic oxidation of n-undecane by various spectral methods. Chromium mass spectral analysis indicates the formation of valeric, hexanoic, heptanoic, octanoic and nonenoic acids, including caprylic anhydride. The NMR spectrum reveals signals from the conversion of the paraffinic hydrocarbon into olefinic and naphthenic groups. It has been determined that in the oxidative system of gamma radicals, great opportunities are created for the formation of oxidation products of various isostructures.

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