Published August 2023, Pg. 34-40
Section: Green energy
UOT: 544.6
DOI: 10.37474/0365-8554/2023-8-34-40
“Green” hydrogen technology for a safe future
V.A. Majidzade PhD in Ch. Sc. - Institute for Catalysis and Inorganic ChemistryThe presented work is focused on the study and search for solving problems in the technology production of “green” hydrogen using solar energy. The analysis of the publications showed that the most promising method for the synthesis of “green” hydrogen is the photoelectrochemical splitting of water, i.e. the electrolysis process using solar energy. This method will also significantly speed up the solution of environmental problems as it is a carbon-free technology. The paper presents the search, synthesis and comparative analysis of electroactive catalysts that meet the current requirements for the process of the water electrolysis under the action of solar energy.
References:
1. Veziroglu T.N., Sahin S. 21st century’s energy: Hydrogen energy system, Energy Conversion and Management 2008, 49(7), pp. 1820-1831.
2. Taghiyev D.B. Hidrogen energetikasy: realliglar, problemler ve inkishaf perspektivleri. https://science.gov.az/az/news/open/18904
3. Fateev V.N., Alexeeva O.K., Korobtsev S.V., Seregina E.A., Fateeva T.V., Grigoriev A.S., Aliyev A.Sh. Problems of accumulation and storage of hydrogen. Chemical Problems, 2018, No. 4 (16), pp. 453-483.
4. Hernandez L.S. New electrodes for low temperature water electrolysis (PEMWE) based on doped tin dioxide aerogels (SnO2 Sb or Ta) as catalyst support. Chemical and Process Engineering. Université Paris sciences et lettres, 2021. English. NNT: 2021UPSLM006.
5. Aliyev A.Sh., Guseynova R.G., Gurbanova U.M., Babanly D.M., Fateev V.N., Pushkareva I.V., Tagiyev D.B. Electrocatalysts for water electrolysis. Chemical Problems, 2018, 16 (3), pp. 283-306 .
6. Pushkarev A.S., Pushkareva I.V., Du Preez S.P., Ivanova N.A., Grigoriev S.A., Slavcheva E.P., Bessarabov D.G., Fateev V.N., Aliyev A.Sh. Iridium catalyst supported on conductive titanium oxides for polymer electrolyte membrane electrolysis. Chemical Problems, 2019, 17 (1), pp. 9-15.
7. Spasov D.D., Mensharapov R.M., Ivanova N.A., Fateeva V.N. Ir spectra study: advantages of methanol vapor feeding for NAFION® membrane structure. Chemical Problems, 2022, 20 (4), pp. 297-304.
8. Safizadeh F., Ghali E., Houlachi G. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions – A Review // Int. J. of Hydrogen Energy, 2015, vol. 40, iss. 1, pp. 256–274.
9. Jaccaud M. Leroux F. Millet J.C. New chlor-alkali activated cathodes. Mater. Chem. Phys. 1989, 22(1), рp.105-119.
10. Wu L., He Y.H., Lei T., Nan B., Xu N.P., Zou J., et al. Characterization of porous Ni3Al electrode for hydrogen evolution in strong alkali solution// Mater. Chem. Phys. 2013, 141(1) pp. 553-561.
11. Bodner M., Hofer A., Hacker V. H2 generation from alkaline electrolyzer// J. Energy and Environment, vol. 4, iss. 4, 2015, pp. 365–381.
12. de Souza R.F., Padilha J.C., Gonçalves R.S., de Souza M.O., Rault-Berthelot J. Electrochemical hydrogen production from water electrolysis using ionic liquid as electrolytes: Towards the best device // J. of Power Sources, 2007, vol. 164, iss. 2, pp. 792–798.
13. Tilak B.V., Tari K., Hoover C.L. Metal anodes and hydrogen cathodes: their activity towards O2 evolution and ClO3 reduction reactions. J. Electrochem. Soc. 1988, 135(6), pp. 1386-1392.
14. Daly P.B., Barry F.J. Electrochemical nickel-phosphorous alloy formation. Int. Mater. Rev., 2003, 48(5), pp. 326-338.
15. Jovic B.M., Lacnjevac U.C., Jovic V.D., Gaji c-Krstaji L.M., Krstajic N.V. On the kinetics of the hydrogen evolution reaction on Ni-MoOx composite catalysts in alkaline solutions. J. Serbian Chem. Soc. 2012, 77(2), pp. 211-224.
16. Gurbanova U.M., Babanly D.M., Huseynova R.G., Tagiyev D.B. Study of electrochemical deposition of Ni-Mo thin films from alkaline electrolytes. Electrochemical Science and Engineering, 2021, 11(1) pp. 39-49.
17. Arul Raj I. Nickel-based, binary-composite electrocatalysts for the cathodes in the energy-efficient industrial production of hydrogen from alkaline-water electrolytic cells. J. Mater. Sci. 1993, 28(16), 4375e82.
18. Cesiulis H., Tsyntsaru N., Budreika A., Skridaila N. Electrodeposition of CoMo and CoMoP alloys from the weakly acidic solutions. Surf. Eng. Appl. Electrochem. 2010, 46(5), pp. 406-415.