Published October 2015

Synthesis of esters with various functional groups

V.M. Abbasov

L.G. Nuriyev

N.F. Sadiyeva

S.A. Iskenderova

L.M. Afandiyeva

E.M. Guliyeva

S.G. Aliyeva

Keywords:  
paraffinic hydrocarbons
ethylene glycol
1.3-butandiol
nano-catalyst
mixed synthesized fatty acids
oxidation
etherification
monoester
polyvinyl chloride
plasticizer
diesel fraction
material balance.

Obtaining of a mixture of synthetic fatty acids by oxidation of paraffinic hydrocarbons separated from diesel fraction is presented. Based on the synthesized acids in the presence of nano-ZnO, the optimal conditions for synthesizing of monoesters of 1.3-etylene glycol and butandiol containing CH3and OH functional groups have been defined. The physical-chemical indicators either used raw material or synthesized esters have been justified via analytical and spectral methods. The material balance of monoesters is presented and the sphere of their application studied.

Links