Published September 2022, Pg. 55-59

Section: Oil refining and petroleum chemistry

UOT: 665.612.2-027.22

DOI: 10.37474/0365-8554/2022-9-55-59

The synthesis of bis-dibenzoat, bis-p-dichloro-dibenzoat ethers of ethylene-glycol in the presence of ionic-liquid catalyst

P.M. Kerimov PhD in Ch. Sc. - Institute for Petrochemical Processes

O.M. Alesgerova PhD in Ch. Sc. - Institute for Petrochemical Processes

L.M. Saadova - Institute for Petrochemical Processes

G.G. Nasibova PhD in Ch. Sc. - Institute for Petrochemical Processes

E.M. Guliyeva PhD in Ch. Sc. - Institute for Petrochemical Processes

Keywords:  
benzoic and p-benzoic acids
ethylene-glycol
ionic liquid
compound ether
antioxidant
diesel fuel

Bis-dibenzoat and bis-p-dichloro-dibenzoat ethers of ethylene-glycol with 82–92 % of yield correspondingly were synthesized based on the benzoic, p-chlorobenzoic acids and ethylene-glycol in the ratio of 2:1,2, at 110 оС temperature and 6-7 hours of reaction duration in the presence of ionic liquid catalyst of n-methylpirralidon-hydrosulphate. The physical-chemical parameters of synthesized compound ethers have been specified and their structure identified spectrally. Synthesized compound ethers have been tested on the steadiness of diesel fuel against thermal oxidation.

References:

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