Published August 2010
Kinetic model for degradation and modification of polyisobutylene with polar monomers under the action of catalysts Friedel - Crafts in solution
Ch.Sh. IbragimovA kinetic model of catalytic destruction and modification of polyisobutylene, which allows to calculate parameters such as molecular weight of the reaction, also the composition of copolymers and the kinetic parameters of rate constants and activation energy. Kinetic model which enables to predict the synthesis of polymers with new physical and chemical properties to calculate all the parameters that affect the process of destruction and modification, to establish any mode of reaction and prove the adequacy of the data obtained by experiments and mathematical processing. The calculation results of the previously derived by our equation using experimental data on modification of polyisobutylene acrylonitrile and vinyl acetate. Adequacy of experimental and calculated data is satisfactory. The results of studies on the effect of each factor on the reaction conditions of vinyl acetate and acrylonitrile in the copolymer.
